Anti-stripping agents for bituminous materials



United States Patent Office 3,249,451 Patented May Ii, 1966 No. 142,493. Divided and this application May 21,

1965, Ser. No. 457,854

16 Claims. (Cl. 106-279) This application is a division of our application Serial No. 142,493, filed October 3, 1961.

This invention relates to novel chemical reaction products and to methods for preparing the novel chemical products which are adapted to be incorporated in bituminous substances such as asphalt to impart thereto improved bonding characteristics.

Bitumen, asphalt, tar and similar asphaltic or bituminous substances are frequently mixed with mineral aggregates such as chips, sand, rock or similar materials to cement the aggregate bodies in a smooth concrete-like paving composition which is utilized for the preparation of roads, dams, airport runways and other structures. In addition, these bituminous substances are frequently employed as coating materials on metals such as pipes and other types of exposed structural parts to waterproof and to protect against corrosion.

In all such applications it is desired that the bituminous substances form a tenacious bond with the material to whichit is applied. It has long been recognized that in the construction of asphalt pavements, water has a detrimental effect on the strength of the bond between the asphalt and mineral aggregate. If the aggregate is wet at the time of application of the asphalt thereto, coating of the aggregate by the asphalt is incomplete. If the coated aggregate is exposed to water shortly after it is coated with the asphalt, separation of the asphalt from the aggregate tends to occur.

To improve the coating and bonding qualities of bituminous compositions several types of chemical additives have been proposed. These chemical additives are generally referred to in the art as anti-stiippants or anti-stripping agents. The anti-stripping agents promote initial adhesion of the asphalt to the aggregate during road construction and cause the asphalt to retain its adhesion to the aggregate after the road has been built. Without the anti-stripping additives, asphalt may be'displaced from aggregate in the road because of ground water and because of the combination of traffic action and rain. Likewise, the anti-stripping agents serve to improve the coating properties of the asphalts when employed in various waterproofing operations, such as canal linings, concrete damproofing and pipeline coatings These asphalt anti-stripping agents must possess a number of desired properties if they are to be accept-able for widespread use. As asphalt anti-stripping additive must be soluble in asphalt, and must not separate on standing. It should have a relatively low melting point, that is, a melting point below about 150 F., and it should not decompose when stored for moderate periods of time at a temperature at which it can be readily pumped and blended. asphalt anti-stripping agent must have surface-active properties, that is, it must lower the interfacial tension between oil and water. This surface active property should be great enough to promote adhesion betwen the asphalt and. aggregate at low concentration of the additive so as not to adversely affect the other physical propertiesof the asphalt. The amount of additive used should be less than about 2% by weight of the treated asphalt. Moreover, the anti-stripping agent should also have enough heat stability to retain its effectiveness after the treated asphalt has been stored for several days at temperatures on the order of about 300 F.

The present invention provides novel reaction products of unsaturated fatty acids which are adapted for incorporation into bituminous substances to impart thereto improved bonding characteristics. The present invention relates also to the method of preparing these new products and to bituminous compositions containing the additives in amounts sufficient to confer improved bonding or antistripping properties to the bituminous composition,

Briefly stated, the new anti-stripping additives of the present invention are produced by treating a relatively long chain unsaturated aliphatic acid with certain oxidizing agents, particularly ozone, followed by condensation of the thus-modified acid at elevated temperatures with an alkylene polya-mine. The new reaction products of unsaturated fatty acids of the present invention possess all of the above-defined properties desired in an anti-stripping additive for bituminous substances such as asphalt.

To prepare the novel products of the present invention an unsaturated fatty acid is treated with ozone, which readily reacts with the unsaturated acid at the location of the double bonds to form an ozonide. This reaction is carried out at room temperatures utilizing a sufiicient amount of ozone to incorporate oxygen in the unsaturated fatty acid material in an amount from about 0.5. to not more than about 6.0% and preferably from 1.5% to 3% by weight. Utilizing oleic acid as a representative acid, this oz-onization reaction may be represented thus:

The above ozonized fatty acid is then reacted at an elevated temperature with an alkylene polyamine. The amount of the alkylene polyamine employed is in excess of the amount theoretically required for reaction with the carboxyl groups present in the acid and ranges from about to 200% by weight theoretical and preferably from about 125 to by Weight theoretical. The reaction is carried out at elevated temperatures on the order of about 120 to 250 C. and preferably from to 250 C. It is believed that the alkylene polyamine reacts with the carboxyl radicals of the ozonized fatty acid to form amine soaps which at the elevated temperatures employed, are dehydrated to amides. The resulting amides in turn con dense with the evolution of water to form imidazoles. The amount of polyalkylene amine which is in excess of that required for reaction with the carboxyl group of the acid reacts with the ozonized fatty acid at the location of the ozonide structure to introduce an amine nitrogen group into the fatty acid hydrocarbon chain. In this manner two hydrophilic amine nitrogen groups are provided in the acid molecule.

The overall reaction involved may be expressed as follows, oleic acid and diethylene triamine being used as representative unsaturated fatty acids and polyamines. (II) 0 Any ethylenically unsaturated or polyunsaturated acid having from about to 22 carbon atoms is suitable for use as the starting material in preparing the reaction products of the present invention. Suitable acids thus include oleic, linoleic, hypogaeic, erucic, linolenic, eleaostearic, lican-ic and the like. Vegetable, animal and marine oils can be used as a source of these fatty acids. Also, commercially available mixtures of such unsaturated acids can be employed, the acid mixture composing tall oil being a preferred starting material for use in the present invention. Tall oil which, is available commercially in various grades is a liquid resin obtained from digesting wood to wood pulp in the paper industry. It is a dark brown viscous liquid with the acid components thereof consisting essentially of 14- to 18 carbon acids. The unsaturated acids oleic and linoleic acids are the predominant acid components. Myristic acid, palmitic acid, heptadecanoic acid, stearic acid, and linolenic acid are usually present as minor constituents. The rosin acids, if any, are present only in small amounts.

The alkylene polyamines that are employed in the present invention for reaction with the ozonized fatty acid are those containing at least two amine groups to the molecule. Examples of such alkylene polyamines that are satisfactory for the purpose are ethylene diamine, propylene-diamine, diethylene triamine, triethylene tetramine and the like.

The imidazoline type anti-stripping agent which is the reaction product of the reaction shown in equation II above can then be reacted with additional quantities of unsaturated aliphatic acids, which acids may be either ozonized orunozonized to form imidazoline-amide type productswhich are also effective anti-stripping agents for asphalt. Such reaction products are also included within the scope of the present invention. The production of these imidazoline amide type reaction products is illustrated by the following reaction.

in an 8 ounce tin and 6 grams of the treated cutback asphalt is Weighed into the tin. The aggregate-asphalt mixture is stirred with a spatula for 3 minutes to insure coating of the aggregate, then the aggregate is placed on a 4 x 4 inch glass plate and allowed to cure at room temperature for 1 hour. After the curing period, the glass plate and coated aggregate are placed in a pan containing enough distilled water to completely cover the aggregate, and allowed to stand for 1 hour. After 1 hour in the distilled water, the percent of asphalt coating the aggregate is visually estimated. Ninety-five percent coating is required to pass the test.

This test plus two modifications of thetest were employed in evaluating the anti-stripping additives of this invention. In the first modification, the additives were mixed with a standard RC-2 or MC3 cutback asphalt 1 Approximately 25 grams of a tall oil fatty acid mixture containing approximately 46% linoleic, 51% oleic and 3% saturated acids were dissolved in from about 5 to ,10 times itsvvolume of a saturated hydrocarbon solvent (Skellysolve C). Ozone was bubbled through the solution at atmospheric pressure and room temperature for varying periods of time, ranging from 7.5 minutes to 1 hour. This rate of ozonization incorporated ozone into the acid molecule in amounts ranging from 0.75% by weight for 7.5 minutes to 6% for 1 hour.

The ozonized tall oil fatty acid mixture was then reacted With an alkylene .polyamine by heating the poly- The invention will be further characterized by the following specific embodiments which illustrate the preparation of the novel anti-stripping agents contemplated by the instant invention and their effectiveness as anti-stripping additives for bituminous substances.

In the following examples, the new products were evaluated as anti-stripping additives for asphalt utilizing the State of Kansas Stripping Test (TS-75) or a modification of this test. 'Briefiy, this test requires that 100 grams of cut-back asphalt and anti-stripping additive be thoroughly mixed, and stored at 300 F. for 72 hours in an 8 ounce paint can. At the end of the storage period, the asphalt-additive mixture is cooled to 125 F., and 6 grams of the mixture is mixed with 100 grams of standard aggregate. The standard aggregate is prepared for the test by weighing 100- grams into a 250 milliliter beaker, covering the aggregate with distilled water and storing at 125 F. for 1 hour. After 1 hour, the excess water is removed by decanting the water through a screenplaced over the top of the beaker, then shaking the aggregate to remove any free water. The wet aggregate is then placed EXAMPLE II Utilizing the procedure of Example I a number of additives were prepared from erucic and ethylene diamine. The amount of ozone incorporated in the acid was varied as shown below, while in each case the amount of ethylene diamine was approximately of theoretical. The RC2 cutback asphalt was made using 72% by weight of a 70-85 penetration asphalt and 28% naptha diluent. The results were as follows:

.ene diamine.

Kanas Stripping Test (TS-J5) [The heat stability portion of the test omitted] 6 had been stored at 300 F. for 72 hours are shown below:

Number Used, Percent Percent Percent Percent Additive Compound Double Wt. Additive Coating Additive Asphalt Additive Coating on Used as Acid bonds Percent in RC-2 Siliceous Outback 1n Outback Standard Aggregate Aggregate .2 9 C RC-2 0.4 99+ -fi ffi j fiifl i 2 93 I MC-3 0. 4 99-100 1 3. O 0, 2 97 K (55.5% J+44.5% Unsaturated 1 4. 5 0.2 99 1O Fatty Acid) 0.4 99-100 1 6. 0 0. 2 45 stripping additives were prepared from distilled tall oil (46% 'linoleic, 51% oleic, 3% saturated acids) and ethyl- The amount of ozone added to the tall oil was varied as shown below, while in each case the amount of ethylene diamine was approximately 170% of theoretical. The same RC-Z cutback asphalt as above was employed. The results were as follows:

Kanas Stripping Test (TS-75 {The heat stability portion of the test omitted] 0 Used, Percent Percent Additive Wt. Additive Coating, Percent in RC-2 Siliceous Asphalt Aggregate EXAMPLE IV Utilizing the procedure as in Example I, antistripping additives were prepared from distilled tall oil and diethylene triamine. Thediethylene triamine was employed in an amount corresponding to about 125% theoretical. These reaction products were tested as antistripping additives in an MC- 3 cutback asphalt Which consisted of 79% by Weight of a 150-200 penetration asphalt and 21% kerosene diluent. The results were as follows:

Wt. percent Percent Additive O3 in Additive Percent Additive in MC-3 ,Coating Asphalt EXAMPLE v Reaction products as prepared in Example IV were further reacted with unsaturated fatty acids. The results of stripping tests run with this type of additive are shown below:

To determine the heat stability of the additives a number of the anti-stripping additives were heated for 72 hours at 300 F. The results of the stripping tests on the experimental additive-asphalt blends after they As seen from the foregoing results, when suitable quantities of the reaction products of the invention, usually from 0.15 to 1.0% by weight, are incorporated in the asphalt it confers on the asphalt the ability to effectively coat Wet aggregates. The improved coating and bonding properties of the asphalt are retained even when it is maintained at elevated temperatures for extended periods of time. the effectiveness of the present compounds is sometimes enhanced by heating the asphalt composition due to the fact that the chemical reaction which forms the antistripping agents initially is rather slow and the period during which they are maintained at elevated temperatures permits the reaction to go to completion. This is seen in the above results in the case of additive K (55.5% J+44.5% unsaturated fatty acid).

The results of the asphalt stripping tests shoWn herein illustrate the anti-stripping characteristics of the additives of this invention. By varying the extent of ozonation the additive characteristics can be matched to the aggregate and to the asphalt which is to be used. This is a particularly advantageous feature since aggregates from diiierent geographical areas seldom have exactly the same stripping characteristics.

The anti-stripping agents of the present invention can be incorporated in bituminous compositions used in the preparation of paving compositions containing the usual types of aggregates such as gravel, crushed stone, sand, slag and the like. Moreover, these aggregates can be employed in either wet or dry condition. Bituminous compositions containing these new anti-stripping agents can be employed as coatings on metals, wood, or other structural materials exposed to water under conditions which tend to cause a loss of strength of the bituminous bond.

Those modifications and equivalents which fall within the spirit of the invention and the scope of the appended claims are to be considered part of the invention.

We claim:

1. A composition comprising a bituminous substance in combination with 0.15 to 1.0 percent by weight of the reaction product prepared by subjecting an unsaturated aliphatic acid of from about 10 to 22 carbon atoms to the action of ozone for a time suiiicient to form an ozonide at the location of the unsaturated carbon-to-car- 'bon bonds in the acid molecule and to incorporate oxygen therein in an amount from about 0.5 to about 6.0% by weight, then reacting the said ozonized unsaturated acid with an alkylene polyamine at a temperature ranging from about 120 to 250 C., the said alkylene polyamine being employed in an amount from about 25- to 100% in excess of that required for reaction with the carboxyl groups in said acid;

2. A composition comprising a bituminous substance in combination with 0.15 to 1.0 percent by weight of the reaction product resulting from the process which comprises subjecting an ethylenically unsaturated acid of 10 to 22 carbon atoms to the action of ozone for a time sufficient to form an ozonide at the location of the unsaturated carbon-to-carbon bonds in the acid molecule and to incorporate oxygen therein in an amount from about 0.5 to about 6.0% by weight, then reacting at a temperature ranging from about to 250 C. and for a time sufficient to form a reaction product said ozonized In fact, it has been found that v unsaturated acid With an alkylene polyamine selected from the group consisting of ethylenediamine and polyethylene polyamines having up to ethylene groups, the said alkylene polyamine being employed in an amount from about 25 to 100% in excess of that required for reaction with the carboxyl groups of said acid.

3. A composition comprising a bituminous substance in combination with 0.15 to 1.0 percent by weight of the reaction product resulting from the process which comprises subjecting tall oil acid mixtures consisting essentially of unsaturated fatty acids of 14 to 18 carbon atoms to the action of ozone for a time sufiicient to form an ozonide at the location of the unsaturated carbon-to-' carbon bonds in the tall oil acid mixtures and to incorporate oxygen therein in an amount from about 0.5 to about 6.0% by weight, then reacting at a temperature ranging from about 120 to 250 C. and for a time suflicient to form a reaction product said ozonized acid mixtures with an alkylene polyamine selected from the group consisting of ethylenediamine and polyethylene polyamines having up to 5 ethylene groups, the said alkylene polyamine being employed in an amount from about 25 to 100% in excess of that required for reaction with the carboxyl groups of said acid.

4, A composition comprising a bituminous substance in combination with 0.15 to 1.0 percent by weight of the reaction product resulting from the process which comprises subjecting tall oil acid mixtures consisting essentially of unsaturated fatty acids of 14 to 18 carbon atoms.

to the action of ozone for a time sufiicient to form an ozonide at the location of the unsaturated carbon-tocarbonbonds in the tall oil acid mixtures and to incorporate oxygen therein in an amount from about 0.5 to about 6.0% by weight, then reacting at a temperature ranging from about 120 to 250 C. and for a time sufficient to form a reaction product said ozonized acid mixtures with diethylenetriamine, the said diethylenetriamine being employed in an amount from about 25 to 100% in excess of that required for reaction with the carboxyl groups of said acid.

5. A composition comprising a bituminous substance in combination with 0.15 to 1.0 percent by weight of the reaction product resulting from the process which comprises subjecting tall oil acid mixtures consisting essentially of unsaturated fatty acids of 14 to 18 carbon atoms to the action of ozone for a time SllffiClEl'lt to form an ozonide at the location of the unsaturated carbon-tocarbon bonds in the tall oil acid mixtures and to incorpo-.

to about 6.0% by weight, then reacting at a temperature ranging from about 120. to 250 C. and for a time sufiicient to form a reaction product said ozonized unsaturated acid with an alkylene polyamine selected from the group consisting of ethylenediamine and polyethylene polyamines having up to 5 ethylene groups, the said alkylene polyamine being employed in an amount from about 25 to 100% in excess of that required for reaction with the carboxyl groups of said acid.

8. An improved bonding composition comprising an asphalt containing from 0.15 to 1.0 percent of the reaction product resulting from the process which comprises subjecting tall oil acid mixtures consisting essentially of unsaturated fatty acids of 14 to 18 carbon atoms to the action of ozone for a time sufficient to form an ozonide at the location of the unsaturated carbon-to-carbon bonds in the tall oil acid mixtures. and to incorporate oxygen therein in an amount from about 0.5 to about 6.0% by weight, then reacting at a temperature ranging from about 120 to 250 C. and for a time sufficient to form a reaction product said ozonized acid mixtures with an alkylene polyamine selected from the group consisting of ethylenediamine and polyethylene polyamines having up to 5 ethylene groups, the said alkylene polyamine being employed in an amount from about 25 to 100% from about 120 to 250 C. and for a time suflicient to form a reaction product said ozonized acid mixtures withethylenediamine, the said ethylenediamine being employed in an amount from about 25 to 100% in excess of that required for reaction with the carboxyl groups of said acid. 1

6. A composition comprising a bituminous substance in combination with 0.15 to 1.0 percent by weight of the reaction product resulting from the process which comprises subjecting an ethylenically unsaturated acid of 10 to 22 carbon atoms to the action of ozone for a time suflicient to form an ozonide at the location of the unsaturated carbon-to-carbon bonds in the acid molecule and to incorporate oxygen therein in an amount from about 0.5 to about 6.0% by weight, then reacting at a temperature ranging from about 120 to 250 C. for a time sufficient to form a reaction product said ozonized unsaturated acid with an alkylene polyamine selected from the group consisting of ethylenediamine and polyethylene polyamines having up to 5 ethylene groups, the said alkylene polyamine being employed in an amount from about 25 to 100% in excess of that required for reaction of carboxyl groups in said acid, and then reacting at an elevated temperature and for a time suflicient to form a reaction product the resulting ozonized acid-alkyl'ene in excess of that required for reaction with the carboxyl groups of said acid.

9. An improved bonding composition comprising an asphalt containing from 0.15 to 1.0 percent of the reaction product resultingtrom the process which comprises subjecting tall oil acid mixtures consisting essentially of unsaturated fatty acids of 14 to 18 carbon atoms to the action of ozone for a time sufiicient-to form an ozonide at the location of the unsaturated carbon-to-carbon bonds in the tall oil acid mixtures and to incorporate oxygen therein in an amount from about 0.5 to about 6.0% by weight, then reacting at a temperature ranging from about 120 to 250 C. and for a time sufficient to form a reaction product said ozonized acid mixtures with diethylenetriamine, the said diethylenetriamine being employed in an amount fromabout 25 to in excess of that required for reaction with the carboxyl groups of said acid.

10. An improved bonding composition comprising an asphalt containing from 0.15 to 1.0 percent of the readtion product resulting from the, process which comprises subjecting tall oil acid mixtures consisting essentially of unsaturated fatty acids of 14 to 18 carbon atoms to the action ofozone for a time sufficient to form an ozonide at the .location of the unsaturated carbon-tocarbon bonds in the tall oil acidmixtures and to incorporate oxygen therein in an amount from about 0.5 to about 6.0% by weight,then reacting at,a temperature ranging from about to 250 C. and for a time suflicient to form a reaction product said ozonized'acid mixtures with ethylenediamine, the said ethylenediamine being employed in an amount from about 25 to 100% in excess of that required for reaction with the carboxyl groups of said acid.

11. An improved bonding composition comprising an asphalt containing from 0.15 to 1.0 percent of the reaction product resulting from the process which comprises subjecting an ethylenically unsaturated acid of 10 to 22 carbon atoms to the action of ozone. for a timesufiicient to form an ozonide at the location of the unsaturated carbon-to-carbon bonds in the acid molecule and to incorporate oxygen therein in an amount from about 0.5 to about 6.0% by weight, then reacting at a temperature ranging from about 120 to 250 C. for a time sufficient to form a reaction product said ozonized unsaturated acid with an alkylene polyamine selected from the group consisting of ethylenediamine and polyethylene polyamines having up to ethylene groups, the said alkylene polyamine being employed in in an amount from about 25 to 100% in excess of that required for reaction of carboxyl groups in said acid, and then reacting at an elevated temperature and for a time suflicient to form a reaction product the resulting ozonized acid-alkylene polyamine product with an additional quantity of an ethylenically unsaturated aliphatic acid of from to 22 carbon atoms.

12. A paving mixture comprising a mineral aggregate with a bituminous material containing from 0.15 to 1.0 percent of the reaction product resulting from the process which comprises subjecting an ethylenically unsaturated acid of 10 to 22 carbon atoms to the action of ozone for a time suflicient to form an ozonide at the location of the unsaturated carbon-to-carbon bonds in the acid molecule and to incorporate oxygen therein in an amount from about 0.5 to about 6.0% by weight, then reacting at a temperature ranging from about 120 to 250 C. and for a time suflicient to form a reaction product said ozonized unsaturated acid with an alkylene polyamine selected from the group consisting of ethylenediamine and polyethylene polyamines having up to 5 ethylene groups, the said alkylene polyamine being employed in an amount from about 25 to 100% in excess of that required for reaction with the carboxyl groups of said acid.

13. A paving mixture comprising a mineral aggregate with a bituminous material containing from 0.15 to 1.0 percent of the reaction product resulting from the process which comprises subjecting tall oil acid mixtures consisting essentially of unsaturated fatty acids of 14 to 18 carbon atoms to the action of ozone for a time suflicient to form an ozonide at the location of the unsaturated carbon-to-carbon bonds in the tall oil acid mixtures and to incorporate oxygen therein in an amount from about 0.5 to about 6.0% by weight, then reacting at a temperature ranging from about 120 to 250 C. and for a time sufficient to form a reaction product said ozonized acid mixtures with an alkylene polyamine selected from the group consisting of ethylenediamine and polyethylene polyamines having up to 5 ethylene groups, the said alkylene polyamine being employed in an amount from about 25 to 100% in excess of that required for reaction with the carboxyl groups of said acid.

14. A paving mixture comprising a mineral aggregate with a bituminous material containing from 0.15 to .,l.O percent of the reaction product resulting from the p'grocess which comprises subjecting tall oil acid mixtures consisting essentially of unsaturated fatty acids of 14 t 18 carbon atoms to the action of ozone for a time stifficient to form an ozonide at the location of the unsaturated carbon-to-carbon bonds in the tall oil acid mixtures and to incorporate oxygen therein in an amount from about 0.5 to about 6.0% by weight, then reacting at a temperature ranging from about 120 to 250 C. and for a time sufiicient to form a reaction product said ozonized acid mixtures with diethylenetriamine, the said diethylenetriamine being employed in an amount from about 25 to in excess of that required for reaction with the carboxyl groups of said acid.

15. A paving mixture comprising a mineral aggregate with a bituminous material containing from 0.15 to 1.0 percent of the reaction product resulting from the process which comprises subjecting tall oil acid mixtures consisting essentially of unsaturated fatty acids of 14 to 18 carbon atoms to the action of ozone for a time sufficient to form an ozonide at the location of the unsaturated carbon-to-carbon bonds in the tall oil acid mixtures and to incorporate oxygen therein in an amount from about 0.5 to about 6.0% by weight, then reacting at a temperature ranging from about to 250 C. and for a time sufiicient to form a reaction product said ozonized acid mixtures with ethylenediamine, the said ethylenediamine being employed in an amount from about 25 to 100% in excess of that required for reaction with the carboxyl groups of said acid.

16. A paving mixture comprising a mineral aggregate with a bituminous material containing from 0.15 to 1.0 percent of the reaction product resulting from the process which comprises subjecting an ethylenically unsaturated acid of 10 to 22 carbon atoms to the action of ozone for a time suflicient to form an ozonide at the location of the unsaturated carbon-to-carbon bonds in the acid molecule and to incorporate oxygen therein in an amount from about 0.5 to about 6.0% by weight, then reacting at a temperature ranging from about 120 to 250 C. for a time sufiicient to form a reaction product said ozonized unsaturated acid with an alkylene polyamine selected from the group consisting of ethylenediamine and polyethylene polyamines having up to 5 ethylene groups, the said alkylene polyamine being employed in an amount from about 25 to 100% in excess of that required for reaction of carboxyl groups in said acid, and then reacting at an elevated temperature and for a time sufiicient to form a reaction product the resulting ozonized acid-alkylene polyamine product with an additional quantity of an ethylenically unsaturated aliphatic acid of from 10 to 22 carbon atoms.

References Cited by the Examiner UNITED STATES PATENTS 1,958,529 5/1934 Bockmuhl et al 260-309 2,149,473 3/1939 Sonn 260-309 2,361,488 10/ 1944 Mikeska 106-273 2,635,079 4/1953 Valko et al 260309.6 2,792,431 5/1957 Niebling et a1. 260-339 2,846,440 5/ 1958 Hughes 260-309.6 2,862,940 12/1958 Otsuki et al. 260-339 2,865,937 12/1958 Maggiolo 260-413 2,894,848 7/1959 Goodwin et al. 106-281 2,897,231 7/ 1959 Niegoroski et a1 260-339 FOREIGN PATENTS 810,571 3/1959 Great Britain.

OTHER REFERENCES Long Chemical Reviews, vol. 27, pages 45559 (1940).

Maggiolo et al. In: Ozone Chemistry and Technology, pages 200-201 (Vol. 21 of Advances in Chemistry Series) Washington, D.C., Amer. Chem. Soc., 1959.

The Condensed Chemical Dictionary. 5th ed., pages 949 and 1061, NY. Reinhold, 1956.

ALEXANDER H. BRODMERKEL, Primary Examiner.

J. B. EVANS, Assistant Examiner. 

1. A COMPOSITION COMPRISING A BITUMINOUS SUBSTANCE IN COMBINATION WITH 0.15 TO 1.0 PERCENT BY WEIGHT OF THE REACTION PRODUCT PREPARED BY SUBJECTING AN UNSATURATED ALIPHATIC ACID OF FROM ABOUT 10 TO 22 CARBON ATOMS TO THE ACTION OF OZONE FOR A TIME SUFFICIENT TO FORM AN OZONIDE AT THE LOCATION OF THE UNSATURATED CARBON-TO-CARBON BONDS IN THE ACID MOLECULE AND TO INCORPORATIVE OXYGEN THEREIN IN AN AMOUNT FROM ABOUT 0.5 TO ABOUT 6.0% BY WEIGHT, THEN REACTING THE SAID OZONIZED UNSATURATED ACID WITH AN ALKYLENE POLYAMINE AT A TEMPERATURE RANGING FROM ABOUT 120 TO 250*C., THE SAID ALKYLENE POLYAMINE BEING EMPLOYED IN AN AMOUNT FROM ABOUT 25 TO 100% IN EXCESS OF THAT REQUIRED FOR REACTION WITH THE CARBOXYL GROUPS IN SAID ACID. 